• 文献标题:   Conductivity and Dielectric Studies of Lithium Trifluoromethanesulfonate Doped Polyethylene Oxide-Graphene Oxide Blend Based Electrolytes
  • 文献类型:   Article
  • 作  者:   AZLI AA, MANAN NSA, KADIR MFZ
  • 作者关键词:  
  • 出版物名称:   ADVANCES IN MATERIALS SCIENCE ENGINEERING
  • ISSN:   1687-8434 EI 1687-8442
  • 通讯作者地址:   Univ Malaya
  • 被引频次:   9
  • DOI:   10.1155/2015/145735
  • 出版年:   2015

▎ 摘  要

Series of polymer blend consisting of polyethylene oxide (PEO) and graphene oxide (GO) as co-host polymer were prepared using solution cast method. The most amorphous PEO-GO blend was obtained using 90 wt.% of PEO and 10 wt.% of GO as recorded by X-ray diffraction (XRD). Fourier transform infrared spectroscopy (FTIR) analysis proved the interaction between PEO, GO, lithium trifluoromethanesulfonate (LiCF3SO3), and ethylene sulfite (ES). Incorporation of 25 wt.% LiCF3SO3 into the PEO-GO blend increases the conductivity to (3.84 +/- 0.83) x 10(-6) S cm(-1). The conductivity starts to decrease when more than 25wt.% salt is doped into the polymer blend. The addition of 1 wt.% ES into the polymer electrolyte has increased the conductivity to (1.73 +/- 0.05) x 10(-5) S cm(-1). Dielectric studies show that all the electrolytes obey non-Debye behavior.