• 文献标题:   N-doped graphene/La0.4Sr0.6Co0.8Ni0.2O3 as an efficient electrocatalyst for oxygen electrode
  • 文献类型:   Article, Early Access
  • 作  者:   WEI CH, LIU JL, HUANG HX, WANG HL, LI CX, WU SL
  • 作者关键词:   perovskite, ndoped graphene, electrocatalyst, oxygen electrode
  • 出版物名称:   IONICS
  • ISSN:   0947-7047 EI 1862-0760
  • 通讯作者地址:  
  • 被引频次:   0
  • DOI:   10.1007/s11581-023-04988-y EA APR 2023
  • 出版年:   2023

▎ 摘  要

The perovskite oxide La0.4Sr0.6Co0.8Ni0.2O3 was prepared by sol-gel method and applied to the oxygen electrode. To further improve its catalytic activity, N-doped graphene (NG) was coupled with La0.4Sr0.6Co0.8Ni0.2O3. The samples were characterized structurally and morphologically using XRD, SEM, and FT-IR. The electrochemical test results showed that the current densities for oxygen evolution reaction (OER) and oxygen reduction reaction (ORR) catalyzed by the hybrid catalyst 10%NG (NG in total catalyst mass ratio of 10%) were 359 mA center dot cm(-2) (0.9 V vs. Hg/HgO) and 393 mA center dot cm(-2) (- 0.6 V vs. Hg/HgO), respectively. The excellent ORR/OER activity and stability of the hybrid catalyst can be attributed to the synergistic effect between La0.4Sr0.6Co0.8Ni0.2O3 and NG.