• 文献标题:   Salt and water co-assisted exfoliation of graphite in organic solvent for efficient and large scale production of high-quality graphene
  • 文献类型:   Article
  • 作  者:   LI JH, YAN HT, DANG DF, WEI W, MENG LJ
  • 作者关键词:   liquidphase exfoliation, coassisted exfoliation, highquality graphene hqgr, large scale production
  • 出版物名称:   JOURNAL OF COLLOID INTERFACE SCIENCE
  • ISSN:   0021-9797 EI 1095-7103
  • 通讯作者地址:   Xi An Jiao Tong Univ
  • 被引频次:   19
  • DOI:   10.1016/j.jcis.2018.09.094
  • 出版年:   2019

▎ 摘  要

Graphene has attracted enormous attention due to its unique physical properties and attractive applications in many fields. However, it is an ongoing challenge to develop a facile and low-cost method for the large scale preparation of high-quality graphene (HQGr). In this work, we have developed an improved liquid-phase exfoliation method to mass produce HQGr. This method is quite simple but efficient by exfoliation of graphite in organic solvent with the co-assistance of sodium citrate and water. Remarkably, the concentration of as-exfoliated HQGr was as high as 0.71 mg/mL under optimal conditions, while the oxygen content in HQGr was only 2.39%. After annealing at 500 degrees C for 2 h in argon atmosphere, the mean conductivity of annealed HQGr was as high as 1.4 x 10(4) S m(-1). Therefore, this facile method for liquid phase exfoliation of graphite has excellent potential in the industrial-scale production of HQGr for numerous applications in energy storage, optical and electronic fields. (C) 2018 Elsevier Inc. All rights reserved.