• 文献标题:   Microwave synthesis of Fe-doped anatase TiO2/N-doped modified graphene composites with superior sodium storage properties
  • 文献类型:   Article
  • 作  者:   WANG SH, ZHU YY, SUN XJ, AN SL, CUI JL, ZHANG YQ, HE WX
  • 作者关键词:   naion batterie, ndoped modified graphene, fedoped anatase tio2, anode
  • 出版物名称:   DIAMOND RELATED MATERIALS
  • ISSN:   0925-9635 EI 1879-0062
  • 通讯作者地址:  
  • 被引频次:   5
  • DOI:   10.1016/j.diamond.2021.108442 EA MAY 2021
  • 出版年:   2021

▎ 摘  要

Exploring advanced anodes for Na-ion batteries (NIBs) remains challenging. This paper reports a simple solgel-microwave two-step route to synthesize Fe-doped anatase TiO2/N-doped modified graphene (FTiO2/NRGO) composites with superior performance in NIBs. The doping of low-valence Fe3+ can generate vacancies in the oxygen sub-lattice of anatase TiO2, thereby improving electronic conductivity. Furthermore, the introduction of N-doped graphene (NRGO) can further enhance the structural stability of the composites and facilitate the ions/Na+ diffusion. With this strategy, the FTiO2/NRGO electrode delivers outstanding reversible capacities (161.3 mAh g(-1) at 0.1 A g(-1) over 300 cycles) and superior rate performance for NIBs (102.1 mAh g(-1) at 2 A g(-1)).