• 文献标题:   Nitrogen-Doped Graphene Nanosheets for Sustainable Removal of Pharmaceutical Contaminants from Water: Kinetics and ANFIS Modeling
  • 文献类型:   Article, Early Access
  • 作  者:   SHARMA J, DUBEY M, CHAKRABARTI S, SRIVASTAVA SK, MISHRA YK, BHATNAGAR A, NIGAM S, JOSHI M
  • 作者关键词:   adsorption, carbon, diclofenac sodium, nitrogendoped graphene nanosheet, wastewater treatment
  • 出版物名称:   CHEMNANOMAT
  • ISSN:   2199-692X
  • 通讯作者地址:  
  • 被引频次:   0
  • DOI:   10.1002/cnma.202300093 EA MAY 2023
  • 出版年:   2023

▎ 摘  要

In this work, nitrogen-doped graphene nanosheets (NGS) were synthesized to remove diclofenac sodium (DFS) from water. The NGS exhibited 99.8 % removal efficiency, adsorption capacity of 278 mg g(-1) for DFS within 30 min, and excellent reusability up to 5 cycles of adsorption. The experimental data fit well with pseudo-second order kinetic model and Langmuir isotherm model. X-ray photoelectron spectroscopy (XPS) and FTIR studies revealed that the carboxylic group, triazine group, graphitic-N, and pyridinic-N groups were involved in the adsorption of DFS. The adaptive neuro-fuzzy inference system (ANFIS) was modeled for accurate prediction of optimizing parameters for the maximum adsorptive removal (%) of DFS by NGS. A subsequent cytotoxicity assay of NGS on a green alga Chlamydomonas sp. signified non-toxic nature. This study suggests NGS to be a promising economic adsorbent for water remediation in resource-poor environments to fulfill "UN-Sustainable Development Goal- 6".