• 文献标题:   The Removal of Single Layers from Multi-layer Graphene by Low-Energy Electron Stimulation
  • 文献类型:   Article
  • 作  者:   JONES JD, SHAH RK, VERBECK GF, PEREZ JM
  • 作者关键词:   thinning, plasma, electron irradiation, graphene, raman spectroscopy
  • 出版物名称:   SMALL
  • ISSN:   1613-6810
  • 通讯作者地址:   Univ N Texas
  • 被引频次:   8
  • DOI:   10.1002/smll.201102350
  • 出版年:   2012

▎ 摘  要

The removal of single atomic layers from multi-layer graphene using a He plasma is reported. By applying sample biases of 60 and +60 V during He plasma exposure, layer removal is found to be due to electrons instead of He ions or neutrals in the plasma. The rate of layer removal depends on exposure time, sample bias, and pre-annealing treatments. Optical contrast microscopy and atomic force microscopy studies show that the removal of C atoms occurs approximately one layer at a time across the entire multi-layer sample with no observable production of large pits or reduction in lateral dimensions. Layer removal is proposed to arise from the electron-stimulated dissociation of C atoms from the basal plane. This process differs from plasma techniques that use reactive species to etch multi-layer graphene.