• 文献标题:   Enhanced mechanical properties of hydrothermal carbamated cellulose nanocomposite film reinforced with graphene oxide
  • 文献类型:   Article
  • 作  者:   GAN S, ZAKARIA S, JAAFAR SNS
  • 作者关键词:   biocomposite, regenerated cellulose membrane, cellulose carbamate, cellulose derivative, nanomaterial
  • 出版物名称:   CARBOHYDRATE POLYMERS
  • ISSN:   0144-8617 EI 1879-1344
  • 通讯作者地址:   Univ Kebangsaan Malaysia
  • 被引频次:   10
  • DOI:   10.1016/j.carbpol.2017.05.056
  • 出版年:   2017

▎ 摘  要

Cellulose carbamate (CC) was synthesized via hydrothermal process and mixed with graphene oxide (GO) to form a homogeneous cellulose matrix nanocomposite films. The properties of CC/GO nanocomposite films fabricated using simple solution-mixing method with different GO loadings were studied. Transmission electron microscope analysis showed the exfoliation of self-synthesized GO nanosheets within the CC matrix. X-ray diffraction results confirmed the crystalline structure of CC/GO films as the CC/GO mass ratio increased from 100/0 to 100/4. The mechanical properties of CC/GO film were significantly improved as compared to neat CC film. From thermogravimetric analysis result, the introduction of GO enhanced the thermal stability and carbon yields. The 3D homogeneous porous structures of the CC/GO films were observed under Field emission scanning electron microscope. These improvements in nanocomposite film properties could be confirmed by Fourier transform infrared spectroscopy due to the strong and good interactions between CC and GO. (C) 2017 Elsevier Ltd. All rights reserved.