• 文献标题:   Resolving the Mechanism of Acoustic Plasmon Instability in Graphene Doped by Alkali Metals
  • 文献类型:   Article
  • 作  者:   MARUSIC L, KALINIC A, RADOVIC I, JAKOVAC J, MISKOVIC ZL, DESPOJA V
  • 作者关键词:   plasmon, acoustic plasmon, graphene, graphene intercalation compound, eels
  • 出版物名称:   INTERNATIONAL JOURNAL OF MOLECULAR SCIENCES
  • ISSN:  
  • 通讯作者地址:  
  • 被引频次:   4
  • DOI:   10.3390/ijms23094770
  • 出版年:   2022

▎ 摘  要

Graphene doped by alkali atoms (AC(x)) supports two heavily populated bands (pi and sigma) crossing the Fermi level, which enables the formation of two intense two-dimensional plasmons: the Dirac plasmon (DP) and the acoustic plasmon (AP). Although the mechanism of the formation of these plasmons in electrostatically biased graphene or at noble metal surfaces is well known, the mechanism of their formation in alkali-doped graphenes is still not completely understood. We shall demonstrate that two isoelectronic systems, KC8 and CsC8, support substantially different plasmonic spectra: the KC8 supports a sharp DP and a well-defined AP, while the CsC8 supports a broad DP and does not support an AP at all. We shall demonstrate that the AP in an AC(x) is not, as previously believed, just a consequence of the interplay of the pi and sigma intraband transitions, but a very subtle interplay between these transitions and the background screening, caused by the out-of-plane interband C (pi) -> A (sigma) transitions.