• 文献标题:   Aqueous Exfoliation of Graphite into Graphene Assisted by Sulfonyl Graphene Quantum Dots for Photonic Crystal Applications
  • 文献类型:   Article
  • 作  者:   ZENG MX, SHAH SA, HUANG DL, PARVIZ D, YU YH, WANG XZ, GREEN MJ, CHENE ZD
  • 作者关键词:   polyaromatic hydrocarbon, graphene quantum dot, surface chemistry, graphene exfoliation, photonic crystal
  • 出版物名称:   ACS APPLIED MATERIALS INTERFACES
  • ISSN:   1944-8244 EI 1944-8252
  • 通讯作者地址:   Texas A M Univ
  • 被引频次:   16
  • DOI:   10.1021/acsami.7b06980
  • 出版年:   2017

▎ 摘  要

We investigate the pi-pi stacking of polyaromatic hydrocarbons (PAHs) with graphene surfaces, showing that such interactions are general across a wide range of PAH sizes and species, including graphene quantum dots. We synthesized a series of graphene quantum dots with sulfonyl, amino, and carboxylic functional groups and employed them to exfoliate and disperse pristine graphene in water. We observed that sulfonyl-functionalized graphene quantum dots were able to stabilize the highest concentration of graphene in comparison to other functional groups; this is consistent with prior findings by pyrene. The graphene nanosheets prepared showed excellent colloidal stability, indicating great potential for applications in "electronics, solar cells, and photonic displays which was demonstrated in this work.