• 文献标题:   In situ low-temperature hydrothermal synthesis of LiMn2O4 nanocomposites based on graphene oxide/carbon nanotubes hydrogel and its capacities
  • 文献类型:   Article
  • 作  者:   WANG KL, HUA L, WANG ZB, JIN GP, CHEN CN
  • 作者关键词:   limn2o4, carbon nanotube, graphene oxide, hydrogel, nanocomposite
  • 出版物名称:   JOURNAL OF MATERIALS RESEARCH
  • ISSN:   0884-2914 EI 2044-5326
  • 通讯作者地址:   Hefei Univ Technol
  • 被引频次:   0
  • DOI:   10.1557/jmr.2020.179
  • 出版年:   2020

▎ 摘  要

Integrating LiMn2O4(LMO) and different carbon materials to build a mixed cathode system can provide fast transport channels to improve the conduction of both electrons and ions. In this paper, our work studied in situ low-temperature hydrothermal synthesis of LMO nanocomposites based on graphene oxide (GO)/carbon nanotubes (CNTs) hydrogel. Compared with the pure LMO nanoparticles, GO/CNTs/LMO (GCLMO) composites greatly improved electrochemical performance in specific capacity, cycle performance and rate ability. The electrochemical test results showed that the specific capacitance of GCLMO nanocomposites reached 396 F/g at the current density of 0.5 A/g, which was much higher than 221 F/g of pure LMO. Even at the current density of 10 A/g, the specific capacitance was still as high as 309 F/g. Besides, after 2000 cycles, the specific capacitance retention of the composite was 93%. Electrochemical data showed that GCLMO composite is an ideal cathode material for supercapacitors.