• 文献标题:   Enhanced photocatalytic degradation of methyl orange by porous graphene/ZnO nanocomposite
  • 文献类型:   Article
  • 作  者:   WANG L, LI Z, CHEN J, HUANG YN, ZHANG HJ, QIU HD
  • 作者关键词:   porous graphene/zno nanocomposite, porous graphene, zno nanoparticle, partial combustion, photocatalytic degradation
  • 出版物名称:   ENVIRONMENTAL POLLUTION
  • ISSN:   0269-7491 EI 1873-6424
  • 通讯作者地址:   Chinese Acad Sci
  • 被引频次:   18
  • DOI:   10.1016/j.envpol.2019.03.071
  • 出版年:   2019

▎ 摘  要

Degrading aquatic organic pollutants efficiently is very important but strongly relied on the design of photocatalysts. Porous graphene could increase photocatalytic performance of ZnO nanoparticles by promoting the effective charge separation of electron-hole pairs if they can be composited. Herein, porous graphene, ZnO nanoparticles and porous graphene/ZnO nanocomposite were prepared by fine tuning of partial combustion, which graphene oxide imperfectly covered by the layered Zn salt was combusted under muffle furnace within few minutes. Resulting ZnO nanoparticles (32-72 nm) are dispersed uniformly on the surface of graphene sheets, the pore sizes of porous graphene are in the range from similar to 3 to similar to 52 nm. The synthesized porous graphene/ZnO nanocomposite was confirmed to show enhanced efficiency under natural sunlight irradiation compared with pure ZnO nanoparticles. Using porous graphene/ZnO nanocomposite, 100% degradation of methyl orange can be achieved within 150 min. The synergetic effect of photocatalysis and adsorption is main reason for excellent MO degradation of PG/ZnO nanocomposite. This work may offer a new route to accurately prepare porous graphene-based nanocomposite and open a door of their applications. (C) 2019 Elsevier Ltd. All rights reserved.