• 文献标题:   Graphene Epitaxy by Chemical Vapor Deposition on SiC
  • 文献类型:   Article
  • 作  者:   STRUPINSKI W, GRODECKI K, WYSMOLEK A, STEPNIEWSKI R, SZKOPEK T, GASKELL PE, GRUNEIS A, HABERER D, BOZEK R, KRUPKA J, BARANOWSKI JM
  • 作者关键词:   graphene, epitaxy, cvd, sublimation, sic, carbon deposition
  • 出版物名称:   NANO LETTERS
  • ISSN:   1530-6984 EI 1530-6992
  • 通讯作者地址:   Inst Elect Mat Technol
  • 被引频次:   211
  • DOI:   10.1021/nl200390e
  • 出版年:   2011

▎ 摘  要

We demonstrate the growth of high quality graphene layers by chemical vapor deposition (CVD) on insulating and conductive SiC substrates. This method provides key advantages over the well developed epitaxial graphene growth by Si sublimation that has been known for decades.(1) CVD growth is much less sensitive to SiC surface defects resulting in high electron mobilities of similar to 1800 cm(2)/(V s) and enables the controlled synthesis of a determined number of graphene layers with a defined doping level. The high quality of graphene is evidenced by a unique combination of angle-resolved photoemission spectroscopy, Raman spectroscopy, transport measurements, scanning tunneling microscopy and ellipsometry. Our measurements indicate that CVD grown graphene is under less compressive strain than its epitaxial counterpart and confirms the existence of an electronic energy band gap. These features are essential for future applications of graphene electronics based on wafer scale graphene growth.