• 文献标题:   Core-shell structured polyethylene glycol functionalized graphene for energy-storage polymer dielectrics: Combined mechanical and dielectric performances
  • 文献类型:   Article
  • 作  者:   LI YC, BI XQ, WANG SS, ZHAN YH, LIU HY, MAI YW, LIAO CZ, LU ZG, LIAO YZ
  • 作者关键词:   functional composite, electrical propertie, mechanical propertie, differential scanning calorimetry dsc
  • 出版物名称:   COMPOSITES SCIENCE TECHNOLOGY
  • ISSN:   0266-3538 EI 1879-1050
  • 通讯作者地址:   Liaocheng Univ
  • 被引频次:   0
  • DOI:   10.1016/j.compscitech.2020.108341
  • 出版年:   2020

▎ 摘  要

Polydispersed graphene was synthesized by grafting a thin layer of water-soluble amine functionalized polyethylene glycol monomethyl ether (PEG-NH2). PEG-NH2 functionalized graphene (PEG@rGO) was then introduced into epoxy resin via a facile solution mixing method. Fourier-transform infrared (FTIR) spectroscopy, Xray photoelectron spectroscopy (XPS) and thermogravimetric analysis (TGA) verified that PEG was successfully grafted to the surface of graphene. The obtained PEG@rGO showed excellent dispersibility in solvents when compared to pristine graphene. As a "core-shell" filler, PEG@rGO filled epoxy nanocomposites displayed improved dielectric constant and reduced dielectric loss, exhibiting potential applications in energy storage capacitors. The mechanical strength and final decomposition temperature were also simultaneously increased.