• 文献标题:   Comparing the Performance of Nb2O5 Composites with Reduced Graphene Oxide and Amorphous Carbon in Li- and Na-Ion Electrochemical Storage Devices
  • 文献类型:   Article
  • 作  者:   HAN XY, RUSSO PA, TRIOLO C, SANTANGELO S, GOUBARDBRETESCHE N, PINNA N
  • 作者关键词:   nb2o5, amorphous carbon, reduced graphene oxide, liion storage, naion storage
  • 出版物名称:   CHEMELECTROCHEM
  • ISSN:   2196-0216
  • 通讯作者地址:   Humboldt Univ
  • 被引频次:   2
  • DOI:   10.1002/celc.202000181
  • 出版年:   2020

▎ 摘  要

Two-dimensional (2D) reduced graphene oxide (rGO) is often combined with metal oxides for energy-storage applications, owing to its unique properties. Here, we compare the electrochemical performance of Nb2O5-rGO and amorphous carbon-coated-Nb2O5 composites, synthesized in similar conditions. The composite made of Nb2O5 and amorphous carbon (using 1,3,5-triphenylbenzene as carbon source) outperforms the Nb2O5-rGO counterpart as a high rate anode electrode material in Li-ion and Na-ion half-cells and hybrid supercapacitors, delivering specific capacities of 134 mAh g(-1) at 25 C against 98 mAh g(-1) for the rGO-based composite (in Li electrolyte) and 125 mAh g(-1) at 20 C against 98 mAh g(-1) (in Na electrolyte). The organic molecules, which are the precursor of the amorphous carbon, control the size and coat the metal oxide particles more efficiently, leading to more extensive carbon-oxide contacts, which benefits the energy-storage performance.