• 文献标题:   beta-Cyclodextrin Anchor NiCo2S4 on Graphene to Enhance Electrochemical Performance of Supercapacitor
  • 文献类型:   Article
  • 作  者:   ZANG XB, LIANG LH, WANG XMZ, LI C, LI PX, SHAO QG, CAO N
  • 作者关键词:   graphene, nickel cobalt sulfide, supercapacitor, betacyclodextrin
  • 出版物名称:   ENERGY TECHNOLOGY
  • ISSN:   2194-4288 EI 2194-4296
  • 通讯作者地址:  
  • 被引频次:   2
  • DOI:   10.1002/ente.202200490 EA AUG 2022
  • 出版年:   2022

▎ 摘  要

To construct high-energy-density supercapacitors, an electrode material with high conductivity needs to be compounded with an electrode material with high capacitive properties. Herein, NiCo2S4-beta-cyclodextrin graphene (CDG) composite material formed by growing NiCo2S4 nanoparticles on graphene oxide (GO) modified with beta-Cyclodextrin (beta-CD) is reported. The modification of beta-CD can tackle the problem of agglomeration of GO and acts as a bridge to increase the binding force between NiCo2S4 nanoparticles and substrates. Combining the benefits of the modified GO and NiCo2S4, the synthesized composite electrode exhibits excellent electrochemical properties of 1325.9 F g(-1) at 1 A g(-1 )and rate capability of 55.5% as current density increases from 1 to 7 A g(-1). Moreover, the asymmetric device, fabricated with NiCo2S4-beta-CDG as the positive electrode and active carbon as the negative electrode, exhibits a maximum energy of 30.72 Wh kg(-1) at 1.28 kW kg(-1) power density.