• 文献标题:   Sodium Intercalation of Graphene Films on Re(10(1)over-bar0 )
  • 文献类型:   Article
  • 作  者:   RUT KOV EV, AFANAS EVA EY, LAVROVSKAYA NP, GALL NR
  • 作者关键词:  
  • 出版物名称:   PHYSICS OF THE SOLID STATE
  • ISSN:   1063-7834 EI 1090-6460
  • 通讯作者地址:   Ioffe Inst
  • 被引频次:   1
  • DOI:   10.1134/S1063783418050268
  • 出版年:   2018

▎ 摘  要

It is shown that during low-temperature (300-500 K) intercalation of sodium atoms into thin multilayer graphene and graphite films on rhenium the first graphene layer plays the role of a trap to which atoms coming on the surface diffuse through a graphite film. The intercalation phase of the interlayer space in the graphite bulk is actively filled at a sodium atoms concentration under the first graphene layer close to the maximum possible (2 +/- 0.5) x 10(14) cm(-2). This phase capacity is proportional to the graphite film thickness that can be varied in this work from one graphene layer to similar to 50 atomic layers. The diffusion energy E (d) of Na atoms through the graphite film was estimated to be E (d) ae 1.4 eV.