• 文献标题:   Ultrathin Ni(OH)(2) layer coupling with graphene for fast electron/ion transport in supercapacitor
  • 文献类型:   Article, Early Access
  • 作  者:   ZHANG XY, WANG HS, SHUI LL, ZHOU GF, WANG X, MA RG, WANG JC
  • 作者关键词:   twodimensional nanomaterial, ni oh 2 nanosheet, graphene, cyanogel synthetic strategy, supercapacitor
  • 出版物名称:   SCIENCE CHINAMATERIALS
  • ISSN:   2095-8226 EI 2199-4501
  • 通讯作者地址:   South China Normal Univ
  • 被引频次:   0
  • DOI:   10.1007/s40843-020-1427-0 EA SEP 2020
  • 出版年:  

▎ 摘  要

Integration of fast electrochemical double-layer capacitance and large pseudocapacitance is a practical way to improve the overall capability of supercapacitor, yet remains challenging. Herein, an effective cyanogel synthetic strategy was demonstrated to prepare ultrathin Ni(OH)(2)nanosheets coupling with conductive reduced graphene oxide (rGO) (rGO-Ni(OH)(2)) at ambient condition. Ultrathin Ni(OH)(2)nanosheet with 3-4 layers of edge-sharing octahedral MO(6)maximally exposes the active surface of Faradic reaction and promotes the ion diffusion, while the conductive rGO sheet boosts the electron transport during the reaction. Even at 30 A g(-1), the optimal sample can deliver a specific capacitance of 1119.52 F g(-1), and maintain 82.3% after 2000 cycles, demonstrating much higher electrochemical capability than bare Ni(OH)(2)nanosheets. A maximum specific energy of 44.3 W h kg(-1)(148.5 W kg(-1)) is obtained, when assembled in a two-electrode system rGO-Ni(OH)(2)//rGO. This study provides an insight into efficient construction of two dimensional hybrid electrodes with high performance for the new-generation energy storage system.