• 文献标题:   Modification of graphene oxide by introduction of allyl acetoacetate functionality and its application as a novel nanoadsorbent in cadmium removal from water
  • 文献类型:   Article
  • 作  者:   AGHDAM K, ALAEI E, PANAHI HA, HASANI AH, MONIRI E
  • 作者关键词:   modified graphene oxide, adsorption, cadmium removal, heavy metals treatment, nanotechnology
  • 出版物名称:   MONATSHEFTE FUR CHEMIE
  • ISSN:   0026-9247 EI 1434-4475
  • 通讯作者地址:   Islam Azad Univ Sci Res Branch
  • 被引频次:   2
  • DOI:   10.1007/s00706-016-1745-3
  • 出版年:   2016

▎ 摘  要

In this study graphene oxide was functionalized by divinylsulfone and allyl acetoacetate conducting a simple route. This novel functionalized graphene oxide [graphene oxide grafted with allyl acetoacetate (GO-GAA)] was characterized by X-ray diffractometry, field emission scanning electron microscopy, and transmission electron microscopy analyses. Thereafter the adsorption property of GO-GAA for Cd2+ ion removal from aqueous media was investigated. The effect of several factors such as pH and temperature on the Cd2+ adsorption was also studied. It was found that the adsorption isotherm follows the Langmuir-Freundlich model and the maximum adsorption capacity was 71 mg/g for GO-GAA toward Cd2+ at 20 A degrees C at pH 7. The fast adsorption kinetics which takes less than 2 min was following the pseudo-first-order model. The synthesized nanoadsorbent also showed a good reusability, even after ten cycles of adsorption-desorption using HNO3 as regenerating agent. Furthermore applicability of synthesized nanoadsorbent for Cd2+ removal from industrial wastewater and well water samples inoculated with cadmium was investigated and over 82 % efficiency was observed.