• 文献标题:   Control over the charge transfer in dye-nanoparticle decorated graphene
  • 文献类型:   Article
  • 作  者:   BONGU SR, VELUTHANDATH AV, NANDA BRK, RAMAPRABHU S, BISHT PB
  • 作者关键词:  
  • 出版物名称:   CHEMICAL PHYSICS LETTERS
  • ISSN:   0009-2614 EI 1873-4448
  • 通讯作者地址:   Indian Inst Technol
  • 被引频次:   1
  • DOI:   10.1016/j.cplett.2015.12.023
  • 出版年:   2016

▎ 摘  要

Charge transfer interaction between silver decorated graphene and three differently charged dyes, cationic (rhodamine 6G), neutral (rhodamine B) and anionic (fluorescein 27) has been studied. The ground state association constants have been evaluated and changes in the fluorescence intensity and lifetimes have been obtained in two solvents. Strength of complex-formation has been found to be higher with the cationic molecule in water. In a higher viscosity solvent, the ground state complex formation is restricted. Local field of localized surface plasmons of nanoparticles adsorbed on the graphene sheets leads to enhanced absorption and fluorescence of fluorescein 27. (C) 2015 Elsevier B.V. All rights reserved.