• 文献标题:   N-Doped Graphene Sheet Encapsulated Sulfur Binary Composite as Cathode for Lithium-Sulfur Battery Applications
  • 文献类型:   Article
  • 作  者:   RAJKUMAR P, DIWAKAR K, KRISHNAVENI K, RADHIKA G, SUBADEVI R, GNANAMUTHU RM, WANG FM, SIVAKUMAR M
  • 作者关键词:   binary composite, cathode material, melt diffusion method, lis battery
  • 出版物名称:   JOURNAL OF MATERIALS ENGINEERING PERFORMANCE
  • ISSN:   1059-9495 EI 1544-1024
  • 通讯作者地址:   Alagappa Univ
  • 被引频次:   0
  • DOI:   10.1007/s11665-020-04825-7 EA MAY 2020
  • 出版年:   2020

▎ 摘  要

Herein, sulfur-/nitrogen-doped graphene (SNG) binary composite has been prepared by melt diffusion method and employed as cathode material for lithium-sulfur (Li-S) battery. The physical and electrochemical performances of prepared SNG binary composite were characterized using x-ray diffraction, Fourier transform infrared spectroscopy, Raman spectroscopy, scanning electron microscope, cyclic voltammetry and galvanostatic charge-discharge test. The SNG cathode delivers a high initial discharge capacity of 1135 mAh g(-1), and it sustains the capacity of 687 mAh g(-1) over the 50th cycle at 0.1C rate. The good electrochemical performance of SNG cathode is accredited to N-doping in graphene, which provides faster charge transfer pathway and suppresses the shuttle effect of polysulfides. The present study determines that the prepared SNG composite is a suitable material for cathode in Li-S battery application.