• 文献标题:   Reduced Graphene Oxide/Mesoporous TiO2 Nanocomposite Based Perovskite Solar Cells
  • 文献类型:   Article
  • 作  者:   HAN GS, SONG YH, JIN YU, LEE JW, PARK NG, KANG BK, LEE JK, CHO IS, YOON DH, JUNG HS
  • 作者关键词:   perovskite solar cell, electron transport layer, reduced graphene oxide, tio2 nanocomposite, charge collection
  • 出版物名称:   ACS APPLIED MATERIALS INTERFACES
  • ISSN:   1944-8244 EI 1944-8252
  • 通讯作者地址:   Ajou Univ
  • 被引频次:   77
  • DOI:   10.1021/acsami.5b06171
  • 出版年:   2015

▎ 摘  要

We report on reduced graphene oxide (rGO)/mesoporous (mp)-TiO2 nanocomposite based mesostructured perovskite solar cells that show an improved electron transport property owing to the reduced interfacial resistance. The amount of rGO added to the TiO2 nanoparticles electron transport layer was optimized, and their impacts on film resistivity, electron diffusion, recombination time, and photovoltaic performance were investigated. The rGO/mp-TiO2 nanocomposite film reduces interfacial resistance when compared to the mp-TiO2 film, and hence, it improves charge collection efficiency. This effect significantly increases the short circuit current density and open circuit voltage. The rGO/mp-TiO2 nanocomposite film with an optimal rGO content of 0.4 vol % shows 18% higher photon conversion efficiency compared with the TiO2 nanopartides based perovskite solar cells.