• 文献标题:   Highly sensitive determination of bisphenol A based on MoCuSe nanoparticles decorated reduced graphene oxide modified electrode
  • 文献类型:   Article
  • 作  者:   DUAN YH, LI S, LEI S, QIAO JT, ZOU LN, YE BX
  • 作者关键词:   reduced graphene oxide, mocuse, bpa, electrochemical sensor
  • 出版物名称:   JOURNAL OF ELECTROANALYTICAL CHEMISTRY
  • ISSN:   1572-6657 EI 1873-2569
  • 通讯作者地址:   Zhengzhou Univ
  • 被引频次:   2
  • DOI:   10.1016/j.jelechem.2018.08.011
  • 出版年:   2018

▎ 摘  要

A new nanocomposite, molybdenum copper selenide (MoCuSe) nanoparticles decorated with reduced graphene oxide (rGO), was successfully prepared by a facile hydrothermal method. The MoCuSe-rGO modified glassy carbon electrode (MoCuSe-rGO/GCE) was fabricated for the first time, which provided a large surface area and exhibited a rapid electron transport rate for the bisphenol A (BPA). The electrochemical behavior of BPA was investigated with various techniques and a new electroanalytical method was established with differential pulse voltammetry. Under optimum conditions, the proposed sensor showed an excellent electrochemical response to BPA with detection limit of 9.0 x 10(-10) mol L-1 and wider linear range of 3.0 x 10(-9) mol x 10(-4) mol L-1. Finally, the proposed method was applied to determine BPA in real samples with satisfactory results. This work might provide a new thought for the development of electrochemical sensors with hybrid materials.