• 文献标题:   Reduced graphene oxide-TiO2/sodium alginate 3-dimensional structure aerogel for enhanced photocatalytic degradation of ibuprofen and sulfamethoxazole
  • 文献类型:   Article
  • 作  者:   NAWAZ M, KHAN AA, HUSSAIN A, JANG J, JUNG HY, LEE DS
  • 作者关键词:   graphene oxide, ibuprofen, sodium alginate, sulfamethoxazole, titanium dioxide, photodegradation
  • 出版物名称:   CHEMOSPHERE
  • ISSN:   0045-6535 EI 1879-1298
  • 通讯作者地址:   Kyungpook Natl Univ
  • 被引频次:   0
  • DOI:   10.1016/j.chemosphere.2020.127702
  • 出版年:   2020

▎ 摘  要

In this study, graphene oxide and titanium dioxide in combination with sodium alginate were used to synthesize the reduced graphene oxide-TiO2 /sodium alginate (RGOT/SA) aerogel. The potential of RGOT/ SA aerogel was evaluated for the photocatalytic degradation of ibuprofen and sulfamethoxazole and was compared with that of bare titanium dioxide nanoparticles. More than 99% removal of both the contaminants was obtained within 45-90 min by using the RGOT/SA aerogel under UV-A light. Mineralization of both the pollutants was also higher in case of RGOT/SA aerogel as compared to bare TiO2 nanoparticles. The optimal mass ratio of TiO2 nanoparticles with respect to graphene oxide was 2:1 in RGOT/SA aerogel in the presence of 1 wt% sodium alginate solution. High photodegradation of Ibuprofen was observed at neutral pH and acidic to neutral pH was found suitable for the photodegradation of sulfamethoxazole. Three-dimensional interconnected macroporous assembly, large surface area for settling TiO2 nanoparticles, efficient charge partitioning, and enhanced physical and chemical adsorption of ibuprofen and sulfamethoxazole on the surface of RGOT/SA aerogel were the significant characteristics of RGOT/SA aerogels. Moreover, ease of separation and recyclability of the RGOT/SA aerogel could further save the extra energy used to separate nanoparticles from the effluent. (C) 2020 Elsevier Ltd. All rights reserved.