• 文献标题:   Coumarin-graphene turn-on fluorescent probe for femtomolar level detection of copper(ii)
  • 文献类型:   Article
  • 作  者:   AKHILA AK, RENUKA NK
  • 作者关键词:  
  • 出版物名称:   NEW JOURNAL OF CHEMISTRY
  • ISSN:   1144-0546 EI 1369-9261
  • 通讯作者地址:   Univ Calicut
  • 被引频次:   3
  • DOI:   10.1039/c8nj04732d
  • 出版年:   2019

▎ 摘  要

Herein, a coumarin-graphene based turn-on fluorescence strategy is proposed for the detection of Cu2+ ions. The interaction of graphene with coumarin reduces the luminescence of the latter and together they constitute a sensor unit. The reduced intensity is restored in the presence of Cu2+ ions owing to the greater affinity of the Cu2+ ions to the graphene compared to coumarin. The proposed mechanism was verified by the reduction of the enhanced luminescence when in contact with a strong complexing agent, EDTA. The sensor displays an outstanding sensitivity and selectivity towards Cu2+ ions over other metal ions in aqueous solution. Under optimised conditions, the calibration curve displays a wide linear range (0-20 M) with a limit of detection of 2 femto molar, which is far below the regulatory level, and admirable when compared to other previously reported systems.