• 文献标题:   Nanoindentation analysis of 3D printed poly(lactic acid)-based composites reinforced with graphene and multiwall carbon nanotubes
  • 文献类型:   Article
  • 作  者:   BATAKLIEV T, GEORGIEV V, IVANOV E, KOTSILKOVA R, DI MAIO R, SILVESTRE C, CIMMINO S
  • 作者关键词:   carbon nanotube, composite, graphene, nanoindentation, poly lactic acid, 3d printing
  • 出版物名称:   JOURNAL OF APPLIED POLYMER SCIENCE
  • ISSN:   0021-8995 EI 1097-4628
  • 通讯作者地址:   Bulgarian Acad Sci
  • 被引频次:   8
  • DOI:   10.1002/app.47260
  • 出版年:   2019

▎ 摘  要

Influences of different nanocomposite loadings in poly(lactic acid) (PLA) matrix on resulting hardness and elasticity were examined in nanoindentation experiments. The following study was focused on the nanomechanical properties of PLA reinforced with graphene nanoplatelets (GNPs) and multiwall carbon nanotubes (MWCNTs) by using Berkovich type pyramidal nanoindenter. A masterbatch strategy was developed to disperse GNP and MWCNT into PLA by melt blending. Young's modulus and nanohardness of as-prepared nanocomposites were characterized as a function of the graphene and carbon nanotubes loading. The nanoindentation analysis reveals that these carbon nanofillers improve the mechanical stability of the nanocomposites GNP/PLA, MWCNT/PLA, and GNP/MWCNT/PLA. That improvement of mechanical properties strongly depends on the fillers content. It was found that the best mechanical performance was achieved for the compound having 6 wt % graphene and 6 wt % MWCNTs in the PLA matrix. The received values for nanohardness and Young's modulus are among the highest reported for PLA-based nanocomposites. (c) 2018 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019, 136, 47260.