• 文献标题:   Fe2O3 particles enwrapped by graphene with excellent cyclability and rate capability as anode materials for lithium ion batteries
  • 文献类型:   Article
  • 作  者:   XIAO W, WANG ZX, GUO HJ, LI XH, WANG JX, HUANG SL, GAN L
  • 作者关键词:   lithium ion batterie, anode, hematite, graphene, hydrothermal method
  • 出版物名称:   APPLIED SURFACE SCIENCE
  • ISSN:   0169-4332 EI 1873-5584
  • 通讯作者地址:   Cent S Univ
  • 被引频次:   64
  • DOI:   10.1016/j.apsusc.2012.11.118
  • 出版年:   2013

▎ 摘  要

A facile hydrothermal method is employed to prepare Fe2O3/graphene composites with different contents of graphene which is determined by thermogravimetric analysis (TG). While the X-ray diffraction (XRD) indicates the presence of hematite, the graphene and Fe2O3 are demonstrated to be existed via Fourier transform infrared spectra (FI-IR) and Raman spectroscopic analysis. Furthermore, the scanning electron microscopy (SEM) and transmission electron microscope (TEM) also illustrate the good combination of graphene and Fe2O3, especially for the composite with graphene mass content of 30%. After performed as anode for lithium ion battery, Fe2O3/graphene composite with graphene mass content of 30% exhibits outstanding cyclability with highly reversible charge capacity of 1069 mAh g(-1) after 50 cycles, at current density of 50 mA g(-1). And when the current density is increased to 1000 mA g(-1), it could still retain charge capacity of 534 mAh g(-1). Meanwhile, the critical role of graphene to the electrochemical performance of composites has also been proven. Crown Copyright (c) 2012 Published by Elsevier B.V. All rights reserved.