• 文献标题:   Removing the residual cellulase by graphene oxide to recycle the bio-polishing effluent for dyeing cotton fabrics
  • 文献类型:   Article
  • 作  者:   WANG R, YANG C, FANG KJ, CAI YQ, HAO LY
  • 作者关键词:   graphene oxide, cellulase, biopolishing effluent, recycling, cotton fabric
  • 出版物名称:   JOURNAL OF ENVIRONMENTAL MANAGEMENT
  • ISSN:   0301-4797 EI 1095-8630
  • 通讯作者地址:   Qingdao Univ
  • 被引频次:   15
  • DOI:   10.1016/j.jenvman.2017.11.056
  • 出版年:   2018

▎ 摘  要

In this research, a stable graphene oxide (GO) suspension was prepared by chemical reduction method from graphite powder. By TEM, the irregular GO sheets with single-atom-layered structure could be observed. The zeta potentials measurement indicated the surface charges of GO were strongly related to pH. BET analysis showed the GO had a specific surface area of 30.7 m(2)/g and pore volume of 0.10 cm(3)/g. When the GO was used to remove the residual cellulase in bio-polishing effluent, it was found the removal capacity reached its maximum value at the pH 4-5. The kinetics studies showed that the removal process of cellulase followed a pseudo-second-order kinetic model with a rate constant (k(2)) of 0.276 x 10(-3) g/mg min and equilibrium adsorption capacity of 278.55 mg/g, respectively. By plotting the adsorption isotherms, it was found the Langmuir model fitted the experimental data well with a cellulase adsorption capacity of 574.71 mg/g, indicating the adsorption of cellulase by GO in a monolayer manner. When dyeing the cotton fabrics with reactive dyes, it was found that the cotton fabrics could acquire similar color properties in the recycled bio-polishing effluent as in fresh water, meaning the effectiveness of removing cellulase by GO and the feasibility of recycling the bio-polishing effluent. (C) 2017 Elsevier Ltd. All rights reserved.