• 文献标题:   New insights into the density of states of graphene oxide using capacitive photocurrent spectroscopy
  • 文献类型:   Article
  • 作  者:   BANSAL T, MOHITE AD, SHAH HM, GALANDE C, SRIVASTAVA A, JASINSKI JB, AJAYAN PM, ALPHENAAR BW
  • 作者关键词:  
  • 出版物名称:   CARBON
  • ISSN:   0008-6223
  • 通讯作者地址:   Univ Louisville
  • 被引频次:   20
  • DOI:   10.1016/j.carbon.2011.09.037
  • 出版年:   2012

▎ 摘  要

Capacitive photocurrent spectroscopy is used to probe the electronic states of graphene-oxide, and reduced graphene-oxide. Three peaks are observed whose intensities scale with the oxygen coverage. The energy of these peaks correlate with the luminescence spectra reported for graphene-oxide. Using a fitting procedure, the density of states for graphene oxide is extracted from the data. It consists of the pi/pi(center dot) states along with a distribution of mid-gap states centered at three different energies near the Dirac point. X-ray photoelectron spectroscopy measurements are used to identify the oxygen functional groups corresponding to the observed state distribution. (C) 2011 Elsevier Ltd. All rights reserved.