• 文献标题:   Effect of graphene oxide on the adsorption properties of ordered mesoporous carbons toward H-2, C6H6, CH4 and CO2
  • 文献类型:   Article
  • 作  者:   SZCZESNIAK B, CHOMA J, JARONIEC M
  • 作者关键词:   ordered mesoporous carbon, graphene oxide, gas adsorption, benzene vapor, hydrogen, carbon dioxide, methane
  • 出版物名称:   MICROPOROUS MESOPOROUS MATERIALS
  • ISSN:   1387-1811 EI 1873-3093
  • 通讯作者地址:   Kent State Univ
  • 被引频次:   8
  • DOI:   10.1016/j.micromeso.2017.10.054
  • 出版年:   2018

▎ 摘  要

Graphene oxide/ordered mesoporous carbon (GO/OMC) nanostructures with narrow mesopore size distribution were obtained via soft-templating synthesis followed by KOH activation. Microporosity and mesoporosity of. these composite nanostructures were additionally controlled by adjusting the amount of added GO and by post-synthesis KOH activation, Incorporation of GO into OMC structure resulted in improving absorption uptakes of benzene and hydrogen, which reached 9.6 mmol/g (at 20 degrees C and pressure close to the saturation vapor pressure) and 11.7 mmol/g (2.3 wt% H-2 at -196 degrees C and 760 mm Hg), respectively. At the same conditions bare activated OMC adsorbed 8.1 mmol/g and 10.8 mmol/g of benzene and hydrogen, respectively. Also, these adsorbents showed high uptakes of CH4 (2.1 mmol/g at 20 degrees C and 760 mm Hg) and CO2 (6.0 mmol/g at 0 degrees C and 760 mm Hg). The GO/OMC composite nanostructures, were characterized by nitrogen adsorption, scanning electron microscopy, Raman spectroscopy and thermogravimetry. To the best of our knowledge, this work represents the, first comparative study of adsorption properties of the GO/OMC composite nanostructures toward various gases.