• 文献标题:   N-Heterocyclic carbene-copper complex supported on ionic liquid-modified graphene oxide: versatile catalyst for synthesis of (i) 1,2,3-triazole and (ii) propargylamine derivatives
  • 文献类型:   Article
  • 作  者:   DABIRI M, ALAVIOON SI, MOVAHED SK
  • 作者关键词:   graphene, carbene ligand, heterogeneous catalysi, copper
  • 出版物名称:   JOURNAL OF THE IRANIAN CHEMICAL SOCIETY
  • ISSN:   1735-207X EI 1735-2428
  • 通讯作者地址:   Shahid Beheshti Univ
  • 被引频次:   1
  • DOI:   10.1007/s13738-018-1435-7
  • 出版年:   2018

▎ 摘  要

A N-heterocyclic carbene-copper complex grafted on graphene oxide with an ionic liquid framework was prepared. The synthesis of (i) 1,2,3-triazole derivatives by 'Click reaction' and (ii) propargylamine derivatives by 'A(3) coupling reaction' in aqueous media by this new catalyst were all successfully accomplished. The catalyst is characterized using infrared spectroscopy, Raman spectroscopy, scanning electron microscopy, thermogravimetric analysis and energy dispersive X-ray spectroscopy, X-ray photoelectron spectroscopy, transmission electron microscopy, and elemental analysis. The catalyst is reused in the ten reaction cycles without considerable loss of catalytic activity. [GRAPHICS]