• 文献标题:   Controllable Magnetism of CoO Nanoparticles Modified by the Reduced Graphene Oxide
  • 文献类型:   Article
  • 作  者:   BI XF, LIU WT, HUANG QS, PANG JH
  • 作者关键词:  
  • 出版物名称:   JOURNAL OF PHYSICAL CHEMISTRY C
  • ISSN:   1932-7447
  • 通讯作者地址:   Sichuan Univ
  • 被引频次:   1
  • DOI:   10.1021/acs.jpcc.5b07151
  • 出版年:   2015

▎ 摘  要

Rocksalt CoO nanopartides (CNPs) have been prepared with a facile solvothermal method. To control the magnetism of CNPs, the reduced graphene oxide (RGO) is adopted to engineer the CNPs. Enwrapped by the atomic-layered carbon sheets, the CNPs can be reduced locally. The CoO/RGO composites were prepared by one-pot and two-pot synthetic methods, respectively. Compared with the CoO/RGO raw composite that have no magnetization hysteresis loop, the weak and the strong hysteresis loops emerged successively via heating the particles at different temperatures and maintaining their nanoscales. The magnetism can be adjusted by controlling the temperature via two routes. By the one-pot synthetic route, the CNPs can be reduced sharply, and an obvious hysteresis is available around 400 degrees C, which is ascribed to the appearance of Co nanodusters decorated in the corners of CNPs. By the two-pot synthetic route, a weak and gradually enhanced hysteresis can be observed, and its magnetic properties should be ascribed to topological defects of RGO. Our findings have opened a new way to acquire nanopartides with controllable magnetism.