• 文献标题:   Preparation and application of magnetic graphene oxide composite for the highly efficient immobilization of U(VI) from aqueous solutions
  • 文献类型:   Article
  • 作  者:   ZHAO DL, CHEN LL, SUN M, LI FF
  • 作者关键词:   graphene oxide, u vi, magnetite, immobilization
  • 出版物名称:   JOURNAL OF RADIOANALYTICAL NUCLEAR CHEMISTRY
  • ISSN:   0236-5731 EI 1588-2780
  • 通讯作者地址:   Anhui Jianzhu Univ
  • 被引频次:   9
  • DOI:   10.1007/s10967-015-4064-y
  • 出版年:   2015

▎ 摘  要

In this present study, a graphene-based magnetic composite (Fe3O4/GO) was prepared and characterized by SEM, TEM, XRD and FTIR. The immobilization of U(VI) onto Fe3O4/GO by a adsorption process was using a batch technique. The pseudo-second-order kinetic and Langmuir isotherm model could best describe the adsorption kinetics and isotherms. The thermodynamic parameters calculated from the temperature dependent adsorption isotherms revealed that the adsorption of U(VI) on Fe3O4/GO was spontaneous and endothermic in nature. The as-prepared Fe3O4/GO composite may be utilized as an efficient, magnetically separable adsorbent for the removal of U(VI) and related radionuclides from aqueous solutions in nuclear waste management.