• 文献标题:   Modulated photoluminescence of graphene quantum dots in the vicinity of an individual silver nano-octahedron
  • 文献类型:   Article
  • 作  者:   WANG WS, HE DW, DUAN JH, FU M, ZHANG XQ, WU HP, HU Y, WANG YS
  • 作者关键词:  
  • 出版物名称:   PHYSICAL CHEMISTRY CHEMICAL PHYSICS
  • ISSN:   1463-9076 EI 1463-9084
  • 通讯作者地址:   Beijing Jiaotong Univ
  • 被引频次:   10
  • DOI:   10.1039/c3cp53660b
  • 出版年:   2014

▎ 摘  要

We propose an effective strategy to enhance and modulate the photoluminescence (PL) of graphene quantum dots (GQDs) in the vicinity of a single silver nano-octahedron (SNO) utilizing three-dimensional finite-difference time-domain calculations. The SNO is designed to act as a multifrequency plasmonic antenna with multiple plasmon resonance modes covering multiple emission peaks of GQDs. The spectral modifications of spontaneous emission are investigated with the variations of the GQD's position and dipole moment orientation relative to the SNO. The PL colour of the GQD can be precisely adjusted between blue and green through the strong interaction with the designed antenna. The multicolour features of GQDs will also facilitate their potential applications as eco-friendly and multifunctional optical probes. The study contributes to a deeper understanding of the PL properties of GQDs near the metallic nanoparticles.