• 文献标题:   Graphene Oxide Foam Supported Titanium( IV): Recoverable Heterogeneous Catalyst for Efficient, Selective Oxidation of Arylalkyl Sulfides to Sulfoxides Under Mild Conditions
  • 文献类型:   Article
  • 作  者:   WANG QH, MA WX, TONG QL, DU GJ, WANG J, ZHANG M, JIANG HL, YANG HL, LIU YX, CHENG MS
  • 作者关键词:  
  • 出版物名称:   SCIENTIFIC REPORTS
  • ISSN:   2045-2322
  • 通讯作者地址:   Shenyang Pharmaceut Univ
  • 被引频次:   2
  • DOI:   10.1038/s41598-017-07590-1
  • 出版年:   2017

▎ 摘  要

An efficient and environmentally friendly method was designed for the oxidation of sulfides to sulfoxides with a recyclable, carbon-skeleton-based heterogeneous catalyst developed by titanium sulfate [Ti(SO4)(2)] mineralization on the surface of graphene oxide foam [Ti(SO4)(2)@GOF] by using 30 wt% H2O2 as oxidant. Several different substituted sulfides were examined to explore the scope of substrates of the selective oxidation. The excellent reusability and durability of Ti(SO4)(2)@GOF was demonstrated by recycling experiments and the catalyst was further applied in the preparation of pantoprazole sodium in a one-pot process.