• 文献标题:   One step electrodeposition of poly-(3,4-ethylenedioxythiophene)/graphene oxide/cobalt oxide ternary nanocomposite for high performance supercapacitor
  • 文献类型:   Article
  • 作  者:   SULAIMAN Y, AZMI MKS, ABDAH MAAM, AZMAN NHN
  • 作者关键词:   ternary nanocomposite, supercapacitor, poly 3 4ethylenedioxythiophene, graphene oxide, cobalt oxide
  • 出版物名称:   ELECTROCHIMICA ACTA
  • ISSN:   0013-4686 EI 1873-3859
  • 通讯作者地址:   Univ Putra Malaysia
  • 被引频次:   7
  • DOI:   10.1016/j.electacta.2017.09.103
  • 出版年:   2017

▎ 摘  要

Poly-(3,4-ethylenedioxythiophene)/graphene oxide/cobalt oxide (PEDOT/GO/Co3O4) nanocomposite was prepared using a single-step electropolymerization technique via chronoamperometry at 1.2 V. Field emission scanning electron microscopy (FESEM) images revealed the presence of Co3O4 nanoparticles on the wrinkled-sheets of PEDOT/GO. The presence of Co3O4 particles in the ternary nanocomposite was proven using Fourier transform infrared spectroscopy (FTIR) and Raman spectroscopy. Ternary PEDOT/GO/Co3O4 nanocomposite electrode displayed better capacitive performances than pure PEDOT and hybrid PEDOT/GO nanocomposite. The ternary nanocomposite electrode exhibited a specific capacitance of 535.60F g(-1) and excellent cycle stability with the capacitance retention of 92.69% after 2000 cycles. PEDOT/GO/Co3O4 possessed much smallest charge transfer resistance (R-ct) and equivalent series resistance (ESR) indicating that the ternary nanocomposite has low charge transfer resistance and excellent electronic conductivity. Thus, PEDOT/GO/Co3O4 could be recommended as an excellent electrode material for high-performance supercapacitor. (C) 2017 Elsevier Ltd. All rights reserved.