• 文献标题:   Bottom-up Approach toward Single-Crystalline VO2-Graphene Ribbons as Cathodes for Ultrafast Lithium Storage
  • 文献类型:   Article
  • 作  者:   YANG SB, GONG YJ, LIU Z, ZHAN L, HASHIM DP, MA LL, VAJTAI R, AJAYAN PM
  • 作者关键词:   nanoribbon, graphene, ultrafast, electrode, lithium ion batterie
  • 出版物名称:   NANO LETTERS
  • ISSN:   1530-6984
  • 通讯作者地址:   Rice Univ
  • 被引频次:   180
  • DOI:   10.1021/nl400001u
  • 出版年:   2013

▎ 摘  要

Although lithium ion batteries have gained commercial success owing to their high energy density, they lack suitable electrodes capable of rapid charging and discharging to enable a high power density critical for broad applications. Here, we demonstrate a simple bottom-up approach toward single crystalline vanadium oxide (VO2) ribbons with graphene layers. The unique structure of VO2-graphene ribbons thus provides the right combination of electrode properties and could enable the design of high-power lithium ion batteries. As a consequence, a high reversible capacity and ultrafast charging and discharging capability is achieved with these ribbons as cathodes for lithium storage. A full charge or discharge is capable in 20 s. More remarkably, the resulting electrodes retain more than 90% of the initial capacity after cycling more than 1000 times at an ultrahigh rate of 190C, providing the best reported rate performance for cathodes in lithium ion batteries to date.