• 文献标题:   A One-Step, Solvothermal Reduction Method for Producing Reduced Graphene Oxide Dispersions in Organic Solvents
  • 文献类型:   Article
  • 作  者:   DUBIN S, GILJE S, WANG K, TUNG VC, CHA K, HALL AS, FARRAR J, VARSHNEYA R, YANG Y, KANER RB
  • 作者关键词:   graphene, graphite oxide, solvothermal, reduced graphene oxide, composite, solar cell, reduction
  • 出版物名称:   ACS NANO
  • ISSN:   1936-0851 EI 1936-086X
  • 通讯作者地址:   Northrop Grumman Corp
  • 被引频次:   404
  • DOI:   10.1021/nn100511a
  • 出版年:   2010

▎ 摘  要

Refiuxing graphene oxide (GO) in N-methyl-2-pyrrolidinone (NMP) results in deoxygenation and reduction to yield a stable colloidal dispersion. The solvothermal reduction is accompanied by a color change from light brown to black. Atomic force microscopy (MM) and scanning electron microscopy (SEM) images of the product confirm the presence of single sheets of the solvothermally reduced graphene oxide (SRGO). X-ray photoelectron spectroscopy (XPS) of SRGO indicates a significant increase in intensity of the bond character, while the oxygen content decreases markedly after the reduction is complete. X-ray diffraction analysis of SRGO shows a single broad peak at 26.24 degrees 20 (3.4 angstrom), confirming the presence of graphitic stacking of reduced sheets. SRGO sheets are redispersible in a variety of organic solvents, which may hold promise as an acceptor material for bulk heterojunction photovoltaic cells, or electromagnetic interference shielding applications.