• 文献标题:   Voltammetric simultaneous determination of catechol and hydroquinone using a glassy carbon electrode modified with a ternary hybrid material composed of reduced graphene oxide, magnetite nanoparticles and gold nanoparticles
  • 文献类型:   Article
  • 作  者:   KONG FY, LI RF, YAO L, WANG ZX, LI HY, LV WX, WANG W
  • 作者关键词:   dihydroxybenzene isomer, environmental contamination, electrochemical sensor, modified electrode, differential pulse voltammetry
  • 出版物名称:   MICROCHIMICA ACTA
  • ISSN:   0026-3672 EI 1436-5073
  • 通讯作者地址:   Yancheng Inst Technol
  • 被引频次:   13
  • DOI:   10.1007/s00604-019-3273-4
  • 出版年:   2019

▎ 摘  要

An electrochemical sensor is described for the simultaneous determination of the pollutants catechol (CC) and hydroquinone (HQ). A glassy carbon electrode (GCE) was modified with reduced graphene oxide, Fe3O4 and gold nanoparticles and then showed a pair of well-defined voltammetric peaks for CC and HQ. Its oxidation peak potentials (located at 0.21 and 0.10V vs. Ag/AgCl) are well separated, and this makes it suitable for simultaneous determination of the two isomers. Under optimal conditions, the oxidation peak currents of CC and HQ increase linearly in the 0.05-550M and 0.1-500M concentration ranges, even in the presence of 0.1mM of the respective other isomer. The detection limits are 0.02 and 0.17M (at S/N=3), respectively. The modified GCE exhibits good selectivity and recovery when applied for the analysis of spiked wastewater.