• 文献标题:   Self-propagating combustion synthesis of few-layer graphene for supercapacitors from CO and Mg
  • 文献类型:   Article
  • 作  者:   XU XY, LAI RX, JIANG CJ, ZHANG WF, LIU L, CAO GP
  • 作者关键词:   graphene, selfpropagating combustion, carbon monoxide, supercapacitor
  • 出版物名称:   JOURNAL OF ALLOYS COMPOUNDS
  • ISSN:   0925-8388 EI 1873-4669
  • 通讯作者地址:  
  • 被引频次:   4
  • DOI:   10.1016/j.jallcom.2022.164652 EA MAR 2022
  • 出版年:   2022

▎ 摘  要

Graphene is considered as a promising electrode material for supercapacitors due to its large specific surface area, excellent electrical conductivity and so on. In this paper, few-layer graphene is prepared by self-propagating combustion reaction between CO and metal magnesium, using powder MgO as deposition template. Graphene with a high specific surface area of up to 928 m(2) g(-1) replicates the morphological feature of powder MgO. Raman spectroscopy analysis demonstrates that the graphene layer decreases when the dosage of MgO template is increased. The specific capacitance of as-prepared sample exhibits the highest specific capacitance of 222 F g(-1) at the current density of 1 A g(-1) in EMI [TFSI] electrolyte. The sample demonstrates a "double high " performance with high specific energy density and high specific power density. A high energy density of 76.3 Wh kg(-1) can be achieved at a specific power density of 1.75 kW kg(-1), and it can still remain 48.6 Wh kg(-1) when the specific power density reaches a high level of 35 kW kg(-1). (C) 2022 Published by Elsevier B.V.