• 文献标题:   Fe3O4 quantum dots on 3D-framed graphene aerogel as an advanced anode material in lithium-ion batteries
  • 文献类型:   Article
  • 作  者:   WANG Y, JIN YH, DUAN YH, JIA MQ
  • 作者关键词:   fe3o4 quantum dot, graphene aerogel, anode material, lithiumion batterie
  • 出版物名称:   IONICS
  • ISSN:   0947-7047 EI 1862-0760
  • 通讯作者地址:   Beijing Univ Chem Technol
  • 被引频次:   2
  • DOI:   10.1007/s11581-017-2044-7
  • 出版年:   2017

▎ 摘  要

Three-dimensional fabricated Fe3O4 quantum dots/graphene aerogel materials (Fe3O4 QDs/GA) were obtained from a facile hydrothermal strategy, followed by a subsequently heat treatment process. The Fe3O4 QDs (2-5 nm) are anchored tightly and dispersed uniformly on the surface of three-dimensional GA. The as-prepared anode materials exhibit a high reversible capacity of 1078 mAh g(-1) at a current density of 100 mA g(-1) after 70 cycles in lithium-ion batteries (LIBs) system. Moreover, the rate capacity still remains 536 mAh g(-1) at 1000 mA g(-1). The enhanced electrochemical performance is attributed to that the GA not only acts as a three-dimensional electronic conductive matrix for the fast transportation of Li+ and electrons, but also provides with double protection against the aggregation and pulverization of Fe3O4 QDs during cycling. Apparently, the synergistic effects of the three-dimensional GA and the quantum dots are fully utilized. Therefore, the Fe3O4 QDs/GA composites are promising materials as advanced anode materials for LIBs.