• 文献标题:   Facile synthesis of pectin-stabilized magnetic graphene oxide Prussian blue nanocomposites for selective cesium removal from aqueous solution
  • 文献类型:   Article
  • 作  者:   KADAM AA, JANG J, LEE DS
  • 作者关键词:   radioactive cesium, magnetic nanoparticle, pectin, graphene oxide, adsorption
  • 出版物名称:   BIORESOURCE TECHNOLOGY
  • ISSN:   0960-8524 EI 1873-2976
  • 通讯作者地址:   Kyungpook Natl Univ
  • 被引频次:   32
  • DOI:   10.1016/j.biortech.2016.05.103
  • 出版年:   2016

▎ 摘  要

This work focused on the development of pectin-stabilized magnetic graphene oxide Prussian blue ( PSMGPB) nanocomposites for removal of cesium from wastewater. The PSMGPB nanocomposite showed an improved adsorption capacity of 1.609 mmol/g for cesium, compared with magnetic graphene oxide Prussian blue, magnetic pectin Prussian blue, and magnetic Prussian blue nanocomposites, which exhibited adsorption capacities of 1.230, 0.901, and 0.330 mmol/g, respectively. Increased adsorption capacity of PSMGPB nanocomposites was attributed to the pectin-stabilized separation of graphene oxide sheets and enhanced distribution of magnetites on the graphene oxide surface. Scanning electron microscopy images showed the effective separation of graphene oxide sheets due to the incorporation of pectin. The optimum temperature and pH for adsorption were 30 degrees C and 7.0, respectively. A thermodynamic study indicated the spontaneous and the exothermic nature of cesium adsorption. Based on non-linear regression, the Langmuir isotherm fitted the experimental data better than the Freundlich and Tempkin models. (C) 2016 Elsevier Ltd. All rights reserved.