• 文献标题:   Determination of the Bending Rigidity of Graphene via Electrostatic Actuation of Buckled Membranes
  • 文献类型:   Article
  • 作  者:   LINDAHL N, MIDTVEDT D, SVENSSON J, NERUSHEV OA, LINDVALL N, ISACSSON A, CAMPBELL EEB
  • 作者关键词:   fewlayer graphene, bending rigidity, buckled membrane
  • 出版物名称:   NANO LETTERS
  • ISSN:   1530-6984 EI 1530-6992
  • 通讯作者地址:   Univ Edinburgh
  • 被引频次:   103
  • DOI:   10.1021/nl301080v
  • 出版年:   2012

▎ 摘  要

Classical continuum mechanics is used extensively to predict the properties of nanoscale materials such as graphene. The bending rigidity, kappa, is an important parameter that is used, for example, to predict the performance of graphene nanoelectromechanical devices and also ripple formation. Despite its importance, there is a large spread in the theoretical predictions of kappa for few-layer graphene. We have used the snap-through behavior of convex buckled graphene membranes under the application of electrostatic pressure to determine experimentally values of kappa for double-layer graphene membranes. We demonstrate how to prepare convex-buckled suspended graphene ribbons and fully clamped suspended membranes and show how the determination of the curvature of the membranes and the critical snap-through voltage, using AFM, allows us to extract kappa. The bending rigidity of bilayer graphene membranes under ambient conditions was determined to be 35.5(-15.0)(+20.0) eV. Monolayers are shown to have significantly lower kappa than bilayers.