• 文献标题:   Helical superstructure of continuum graphene cone uncovered by TEM analysis of herringbone-striped pattern in graphitic whiskers
  • 文献类型:   Article
  • 作  者:   SAITO Y, NISHIOHAMANE D
  • 作者关键词:   helical superstructure, growth model, striped lattice image, coiled graphene cone
  • 出版物名称:   JOURNAL OF CRYSTAL GROWTH
  • ISSN:   0022-0248 EI 1873-5002
  • 通讯作者地址:   Univ Tokyo
  • 被引频次:   1
  • DOI:   10.1016/j.jcrysgro.2016.06.037
  • 出版年:   2016

▎ 摘  要

Cone-shaped graphitic whiskers (CGWs) are a form of pyrolytic carbon, consisting of conically stacked hexagonal carbon layers with an apex angle of similar to 135-140 degrees. Under transmission electron microscopy (TEM), CGWs often exhibit herringbone-striped patterns. Bright-field (BF) and dark-field (DF) TEM images indicated that the stripes are due to periodical appearance of a strong inter-planar reflection, which is consistent with helical rotation of layers with stepwise "layer overlap". High-resolution TEM revealed that the period was similar to 14-15 layers. The relationship between apex angle and stripe periodicity of CGWs could be consistently explained in terms of a helical superstructure of tightly coiled continuous graphene cone. (C) 2016 Elsevier B.V. All rights reserved.