• 文献标题:   Ultra-long MnO2 nanowire-entrenched reduced graphene oxide composite electrodes for energy storage
  • 文献类型:   Article
  • 作  者:   ROSAIAH P, DIVYA P, PRAKASH NG, DHANANJAYA M, SAMBASIVAM S, ALASBAHI BA, SHAIK DPMD, KO TJ
  • 作者关键词:   supercapacitor, mno2, nanorod, nanowire, electrochemistry
  • 出版物名称:   DIAMOND RELATED MATERIALS
  • ISSN:   0925-9635 EI 1879-0062
  • 通讯作者地址:  
  • 被引频次:   1
  • DOI:   10.1016/j.diamond.2023.109709 EA JAN 2023
  • 出版年:   2023

▎ 摘  要

Supercapacitors are particularly interested in low-dimensional materials. Herein, MnO2 nanorods and ultralong MnO2 nanowires (NWs) were synthesized along with reduced graphene oxide (rGO) via a simple hydrothermal method. MnO2 NWs/MnO2 NRs crystallize with a low diameter of 20-30 nm when synthesized in situ with rGO. The basic crystallographic structure and chemical state of the composites were investigated using XRD, Raman, and XPS. The MnO2 NWs/rGO composite had the highest specific capacitance (Cs) of 536 Fg(-1) at a current density of 1 Ag-1 with an outstanding capacitance retention of 92.3 % over 10,000 cycles, which is much su-perior than the pure MnO2 NWs/MnO2 NRs and MnO2 NRs/rGO composites. Moreover, MnO2 NWs/rGO com-posites demonstrated excellent rate performance by sustaining a specific capacitance of 321 F g(-1) even at high current density of 5 A g(-1), which is 60 % of its initial capacitance. Therefore, present strategy is the most viable option for fabricating high-performance electrode materials to address practical concerns of supercapacitors.