• 文献标题:   Graphene oxide/N-methyl-2-pyrrolidone charge-transfer complexes for molecular detection
  • 文献类型:   Article
  • 作  者:   XIN GQ, GONG SY, KIM N, KIM J, HWANG W, NAM J, CHO YH, CHO SM, CHAE H
  • 作者关键词:   graphene, graphene oxide, chargetransfer complex, molecular sensor, timeresolved photoluminescent spectra
  • 出版物名称:   SENSORS ACTUATORS BCHEMICAL
  • ISSN:   0925-4005
  • 通讯作者地址:   Sungkyunkwan Univ
  • 被引频次:   4
  • DOI:   10.1016/j.snb.2012.09.003
  • 出版年:   2013

▎ 摘  要

Charge transfer complex (CTC) has been formed between photoluminescent graphene oxide (GO) as electron acceptor and N-methylpyrrolidone (NMP) as electron donor. Studies of UV absorption and photoluminescence (PL) suggest that the formation of CTC results in a red-shift of absorption and a new PL emission. Decay dynamics was described by time-resolved PL spectra and a clear ultrafast charge-transfer process was observed from the PL rise times. The PL of the CTC was sensitive to external components, allowing molecular detection of 7,7,8,8-tetracyanoquinodimethane and 1,3,5-trinitrobenzene up to hundred nanomolar concentration levels through the photoluminescence signals. (C) 2012 Elsevier B.V. All rights reserved.