• 文献标题:   Mesoporous Manganese Sulfide Spheres Anchored on Graphene Sheets as High-Capacity and Long-Life Anode Materials for Lithium-Ion Batteries
  • 文献类型:   Article
  • 作  者:   CHEN DZ, QUAN HY, HUANG ZN, GUO L
  • 作者关键词:   anode material, graphene, lithiumion batterie, manganese sulfide, mesoporous material
  • 出版物名称:   CHEMELECTROCHEM
  • ISSN:   2196-0216
  • 通讯作者地址:   Nanchang Hangkong Univ
  • 被引频次:   20
  • DOI:   10.1002/celc.201500171
  • 出版年:   2015

▎ 摘  要

A novel porous manganese sulfide/graphene composite was prepared by a simple in situ solvothermal approach. These mesoporous manganese sulfide sub-microspheres with an average diameter of 700 nm were anchored homogeneously onto graphene nanosheets. Such a special microstructure not only effectively alleviates the mechanical strain of the electrode upon lithiation/delithiation, but it also improves contact be-tween the electrode materials and the electrolyte. As a result, the composite exhibits a high Li-ion storage capacity and excellent cycling stability as an anode material for lithium-ion batteries. At a current of 50 mAhg(-1), the material delivers a reversible capacity up to 1231 mAhg(-1); at a current density of 0.2 Ag-1, the material still retains a reversible capacity of 735 mAhg(-1) after 300 cycles.