• 文献标题:   Partially Oxidized Graphene/Metallic Single-Walled Carbon Nanotubes Film-Coated Electrode for Nanomolar Detection of Dopamine
  • 文献类型:   Article
  • 作  者:   SUNDRAMOORTHY AK, GUNASEKARAN S
  • 作者关键词:   metallic singlewalled carbon nanotube, oxidized graphene, dopamine detection, electrocatalyst, biosensor
  • 出版物名称:   ELECTROANALYSIS
  • ISSN:   1040-0397 EI 1521-4109
  • 通讯作者地址:   Univ Wisconsin
  • 被引频次:   15
  • DOI:   10.1002/elan.201500047
  • 出版年:   2015

▎ 摘  要

Enriched metallic single-walled carbon nanotubes (mSWCNTs) were dispersed in aqueous solution of partially oxidized graphene (po-Gr). As-prepared po-Gr/mSWCNTs suspension was used to modify glassy carbon electrode (GCE) surface, which showed high electrocatalytic activity for dopamine (DA) oxidation in pH 7.0 phosphate buffered saline (PBS) solution. Using po-Gr/mSWCNTs/GCE we could detect DA from 350 to 3600 nM, with a detection limit down to 25 nM in physiological condition (in pH 7.0 PBS); whereas, po-Gr/GCE (without mSWCNTs) and bare GCE produced measurable signals only at or above 200 nM DA. Thus, the po-Gr/mSWCNTs film we fabricated is a promising nanomaterial for fabrication of biosensors for nanomolar detection of DA.