• 文献标题:   Versatile p-Type Chemical Doping to Achieve Ideal Flexible Graphene Electrodes
  • 文献类型:   Article
  • 作  者:   HAN TH, KWON SJ, LI NN, SEO HK, XU WT, KIM KS, LEE TW
  • 作者关键词:   chemical doping, flexible oled, graphene, transparent electrode
  • 出版物名称:   ANGEWANDTE CHEMIEINTERNATIONAL EDITION
  • ISSN:   1433-7851 EI 1521-3773
  • 通讯作者地址:   Pohang Univ Sci Technol POSTECH
  • 被引频次:   37
  • DOI:   10.1002/anie.201600414
  • 出版年:   2016

▎ 摘  要

We report effective solution-processed chemical p-type doping of graphene using trifluoromethanesulfonic acid (CF3SO3H, TFMS), that can provide essential requirements to approach an ideal flexible graphene anode for practical applications: i) high optical transmittance, ii) low sheet resistance (70% decrease), iii) high work function (0.83 eV increase), iv) smooth surface, and iv) air-stability at the same time. The TFMS-doped graphene formed nearly ohmic contact with a conventional organic hole transporting layer, and a green phosphorescent organic light-emitting diode with the TFMS-doped graphene anode showed lower operating voltage, and higher device efficiencies (104.1 cd A(-1), 80.7 lm W-1) than those with conventional ITO (84.8 cd A(-1), 73.8 lm W-1).