• 文献标题:   In situ prepared reduced graphene oxide/CoO nanowires mutually-supporting porous structure with enhanced lithium storage performance
  • 文献类型:   Article
  • 作  者:   LENG XN, DING XD, HU JJ, WEI SF, JIANG ZH, LIAN JS, WANG GY, JIANG Q, LIU JA
  • 作者关键词:   in situ, graphene, coo nanowire, lithium ion batterie
  • 出版物名称:   ELECTROCHIMICA ACTA
  • ISSN:   0013-4686 EI 1873-3859
  • 通讯作者地址:   Jilin Univ
  • 被引频次:   33
  • DOI:   10.1016/j.electacta.2015.12.190
  • 出版年:   2016

▎ 摘  要

An efficient method is demonstrated to synthesize reduced graphene oxide/Co nanowires (rGO/CoO) mutually-supporting porous structure, which is in situ prepared by annealing self-assembled graphene oxide (GO)/Co(CO3)(0.5)(OH).0.11H(2)O nanowires composite in N-2 atmosphere. The CoO nanowires are uniformly and tightly anchored on the rGO sheet surface, preventing the aggregation of the CoO nanowires and the restacking of rGO sheets. As an anode material for lithium ion batteries (LIBs), rGO/CoO electrode displays excellent electrochemical performance including a high reversible capacity of 994 mA h g (1) even after 100 cycles with 96.3% capacity retention of the initial discharge capacity, super rate capability (718, 577, 504, 388 and 262 mA hg (1) 0.8, 3.2, 5, 7 and 10C, respectively,1C = 1 A g (1)) and extremely excellent cycling performance at high rates (621 mA h g I at 1C after 620 cycles; 520 mA h g (1) at 3C even after 750 cycles). (C) 2015 Elsevier Ltd. All rights reserved.