• 文献标题:   Columnar assembly and successive heating of colloidal 2D nanomaterials on graphene as an efficient strategy for new anode materials in lithium ion batteries: the case of In2S3 nanoplates
  • 文献类型:   Article
  • 作  者:   CHOI J, JIN J, LEE J, PARK JH, KIM HJ, OH DH, AHN JR, SON SU
  • 作者关键词:  
  • 出版物名称:   JOURNAL OF MATERIALS CHEMISTRY
  • ISSN:   0959-9428 EI 1364-5501
  • 通讯作者地址:   Sungkyunkwan Univ
  • 被引频次:   25
  • DOI:   10.1039/c2jm30949a
  • 出版年:   2012

▎ 摘  要

This study shows that heat-treatment of colloidal inorganic nanoplates with columnar assembly under argon is a good strategy for development of anode materials. The heating of colloidal In2S3 nanoplates under argon resulted in the formation of film-like materials through interconnection of plates in a side by side manner. When the columnarly assembled colloidal In2S3 plates were heated at 400 degrees C under argon for 2 hours on graphene, more efficient anode materials with smaller diameters were obtained. Interestingly, the heat-treated columnarly assembled In2S3 plates on graphene had a layered structure, which was attributed to the possible existence of carbon materials between plates formed by the heat-treatment of surfactants under argon. The resultant graphene-In2S3 composites showed enhanced discharge capacities, up to 716-837 mA h g(-1), as well as excellent stabilities. In addition, the materials showed promising coulombic efficiencies and rate performances. We believe that, based on the strategy in this work, diverse graphene-inorganic nanomaterial composites with a layered structure can be prepared and applied as new anode materials in lithium ion batteries.